As shown in Episode 32 of Duel Masters Versus, this storyline follows the events of the Duel Masters: Star Cross manga instead of Cross Shock. It introduces a new protagonist named Katta Kirifuda, the brother of Shobu. He wants to be a dueling champion like his brother Shobu, but in his own way. The series shows the beginning of his dueling adventures with his friends, Bucyake, Yohdel and Benchan. During these adventures he considers Dragon Ryu a fierce duelist as his rival. This series also features the story behind the battle between the races of Hunters and Aliens.
E2 · Teach Me the Rules!
E10 · The Card of Victory!
E16 · Showdown at Dash HQ!
E18 · The Surreal Intense Duel
E19 · Master Katta!
E20 · The DM Gorillas!!
E21 · Benchan's Confession
E26 · Finals Ticket!
E30 · Believe, Katta!
E32 · One More Plan!
E38 · Who Needs Dueling?
E42 · That's Our Duel Hero!
E50 · Last Turn of Destiny!
E52 · We're Duel Masters Now!!